资源、生态与环境

地下水硝酸盐污染研究综述

展开
  • 中山大学地理科学与规划学院, 广州 510275
陈建耀(1966-),教授,博导,E-mail:chenjyao@mail.sysu.edu.cn

收稿日期: 2005-06-01

  修回日期: 2005-12-01

  网络出版日期: 2006-01-25

基金资助

本研究得到国家自然科学基金(40571027),"985工程"GIS与遥感的地学应用科技创新平台(项目编码105203200400006)及留学回国人员科研启动基金资助.

Overview on the Studies of Nitrate Pollution in Groundwater

Expand
  • School of Geography and Planning, Sun Yat-sen University, Guangzhou 510275, China

Received date: 2005-06-01

  Revised date: 2005-12-01

  Online published: 2006-01-25

摘要

地下水为重要的资源,一旦受污染,将难以更新与恢复。近年来,地下水硝酸盐污染问题正日益受到国内外研究者的关注。关于这方面的研究主要在以下方面:地下水硝酸盐的转化过程与机理;地下水硝酸盐污染的来源以及避免污染的方法措施;地下水硝酸盐氮、亚硝酸盐氮的确定方法;如何减少或者除去地下水中的硝酸盐;另外还有一些地下水硝酸污染与人体健康的研究等。在综述有关文献的基础上,提出未来地下水硝酸盐污染的三个方向:水与硝酸盐运移的耦合;界面过程;人文影响与全球角度。

本文引用格式

陈建耀,王 亚,张洪波,赵新峰 . 地下水硝酸盐污染研究综述[J]. 地理科学进展, 2006 , 25(1) : 34 -44 . DOI: 10.11820/dlkxjz.2006.01.004

Abstract

More than 90 papers of the last 20 years on nitrate pollution in groundwater were reviewed, and the issue both in China and abroad was found focusing on the following aspects: the transform processes and mechanism of nitrate in groundwater, the form of pollution and the sources of nitrate, and the methods to avoid and treat nitrate pollution. The transform processes include: mineralization-immobilization, fixation, nitrification and denitrification. All kinds of nitrate are classified into point origin and area origin. There are two approaches, structural approache and non-structural approache, reported to deal with nitrate pollution in groundwater. The structural approach was well reported to dispose of nitrate in a local or point scale, while the non-structural approach could be adopted in the regional scale, but few case studies were reported. Techniques to treat nitrate pollution were well reported in China, e.g. carbon dioxide regenerated ion exchanger, bio-film-electrode process, etc. Nitrate pollution in groundwater is closely related to human activities, and the main sources of nitrate were identified as excessive application of commercial fertilizers, manure, and the irrigation by non-treated wastewater, etc. The main factors affecting the occurrence, distribution and change of nitrate in groundwater were identified as: · Dramatic increasing in population that requires much more food supply, · Urbanization that discharges too much waste to be absorbed by soil and water bodies, · Over use of fertilizer, · Poor management in water and land resources, · Land use and land cover change, · Public concern and policy issues, · Change in global food production and trade Three themes were thus proposed for further study in nitrate, given as follows: 1. Integration of nitrogen and water cycle and processes, with respect to nitrogen aspects of hydrological cycle (NAHC); 2. Interface processes and mechanism regarding nitrate transformation in soil, plant, atmosphere and groundwater; 3. Impacts of nitrate in groundwater in the interaction of land and ocean, and assessment of human activities, such as urbanization, food production and trade, on the change of nitrate in groundwater in the global perspective.

参考文献


[1] Clark I D, Fritz P. Environmental isotopes in hydrogeology. Lewis Publishers, Boca Raton, 1997, 148~154 &172~186.

[2] 阮晓红 等. 氮在饱和土壤层中迁移转化特征研究. 河海大学学报, 1996,24(2).

[3] 吴耀国. 地下水环境中反硝化作用. 环境污染治理技术与设备, 2002,3(3).

[4] Shearer G, D H. Kohl and S H Chien. The nitrogen-15 abundance in a wide variety of soils. Soil Sci. Soc. AM. J., 1982,42: 899~902.

[5] Linn D M, J W Doran. Effect of water-filled pore space on CO2 and N2O production in tilled and nontilled soils. Soil Sci. Soc. Am. J. 1982,48: 1267~1272.

[6] Broadbent F E,K B Tyler. Effect of pH on nitrogen immobilization in two California soils. Plant and Soil, 1965,23: 314~422.

[7] Stanford G, S J Smith. Nitrogen mineralization potentials in soil. Soil Sci. Soc. Am. Proc., 1972,36: 465~472.

[8] 董悦安 等. 农田区地下水氮污染和氮转化的实验研究. 北京师范大学学报(自然科学版),2001,37(2).

[9] van Genuchten, M.Th. and P.J. Wierenga. Mass transfer studies in sorbing porous media. I. Analytic solutions. Soil Sci. Soc. Am. Proc. 1976,40: 473~480.

[10] van Genuchten, M.Th., P.J. Wierenga and G.A. O'Connor. Mass transfer studies in sorbing porous media. II. Experimental Evaluation with 2,4,5-T. Soil Sci. Soc. Am. J.,1977, 41: 278~285.

[11] Jury, W.A. and D.R. Nielson. Nitrate transport and leaching mechanisms, In: Nitrogen Management and Ground Water Protection, edited by R.F. Follett, Elsevier, 1989,139~160.

[12] Geng Q Z, G Girard, E Ledoux. Modeling of nitrogen cycle and nitrate transfer in regional hydrogeologic systems. Ground water, 1996,34(2): 293~304.

[13] Gallbally I E, C R Roy, C M. Elsworth, and H.A.H. Rabich. The measurement of nitrogen oxide (NO, NO2) exchange over plant/soil surfaces. CRISO Aust. Div. Atmos. Res. Tech. Pap. No. 1985,8: 1~23.

[14] 张思聪 等. 唐山平原区地下水硝酸盐污染变化趋势的研究. 水利发电学报, 2002,(1).

[15] 吉田和広、小倉紀雄. 野川湧水中の硝酸盐浓度とその起源、地球科学, 1978,12:44~51.

[16] 平田健正 編著. 土壌·地下水汚染と対策、日本环境测定分析协会, 1996.

[17] 新井秀子, 田溂则雄. 安定同位体を利用した河川浄化机能の评价、环境科学会志, 1992,5(4): 249~258.

[18] Starr R C, R W Gillham. Denitrification and organic carbon availability in two aquifers. Ground water, 1993,31( 6):934~947.

[19] 胡克林,李保国 等. 区域浅层地下水埋深和水质的空间变异性特性. 水科学进展, 2000,11(4).

[20] 胡克林, 李保国 等. 区域浅层地下水硝酸盐含量评价的指示克立格法. 水利学报, 2001年3月.

[21] 肖智毅. 海淀区地下水硝酸盐污染及其影响因素. 环境与健康杂志, 2003, 20(3).

[22] 李文庆 等. 大棚土壤硝酸盐状况研究. 土壤学报, 2002, 39(2).

[23] 刘愿英 等. 水井污染与井到化粪池间距的季节相关性, 杨凌职业技术学院学报, 2002, 1(1).

[24] 赵燮京 等. 成都平原农区地下水中NO3—N含量变化规律研究. 土壤学报, 2004, 41(1).

[25] Hallberg G R. Nitrate in ground water in the United States, In: Nitrogen Management and Ground Water Protection, edited by R.F. Follett, Elsevier, 1989, 35~74.

[26] Follett R F. Ground water quality concerns about nitrogen, In: Nitrogen Management and Ground Water Protection, edited by R.F. Follett, Elsevier, 1989, 1~34.

[27] Massone H E, Martinez D E, Cionchi J L, Bocanegra E. Surburban areas in developing countries and their relationship to groundwater pollution: a case study of Mar del Plata, Argentina. Environmental Management, 1998, 22(2): 245~254.

[28] Smith G D, Wetselaar R, Fox J J, van de Graaff R H M, Moeljohardjo D, Sarwono J, Wiranto Asj’ari S R, Tjojudo S and Basuki. The origin and distribution of nitrate in groundwater from village in Kotagede, Yogyakarta, Indonesia. Hydrogeology Journal, 1999, 7 (6): 576~589.

[29] Afzal S, Ahmad I, Younas M, Zahid M D, Khan M H, Ijaz A and Ali K. Study of water quality of Hudiara drain, India-Pakistan. Environment International, 2000, 26: 87~96.

[30] Mitra A. and Gupta S.K. Evaluation of groundwater pollution potential of sewage-irrigated vegetable growing areas of the eastern fringe of Calcutta City. Schriftenreihe Des Vereins Fur Wasser-, Boden-Und Lufthygiene, 2002, 105: 261~267.

[31] Rashed M, Awad S R, Salam M A. and Smidt E. Monitoring of groundwater in Gabal el Asfar wastewater irrigated area (Greater Cairo). Water Science and Technology, 1995, 32: 163~169.

[32] Chen JY, Tang CY, Sakura S, Yu JJ, Fukushima, Y. Nitrate pollution from agriculture in different hydrogeological zones of the regional groundwater flow system in the North China Plain, Hydrogeology Journal , 2005, 13:481~492.

[33] Chen JY, Tang CY, Shen YJ, Sakura Y, Kondoh A. Nitrate pollution of groundwater in a wastewater irrigated field of Hebei Province, In Risk Assessment of Waste Water Re-Use on Groundwater Quality, Joop Steenvoorden (ed.). Red-book of IAHS, 2004, 285:23~27.

[34] 张维理 等. 我国北方农用氮肥造成地下水硝酸盐污染的调查. 植物营养与肥料学报, 1995, 1(2).

[35] 尉元明 等. 甘肃不同生态区化肥施用量对农业环境的影响. 干旱地区研究, 2004, 21(1).

[36] 高阳俊 等. 滇池流域地下水硝酸盐污染现状分析. 云南地理环境研究, 2003, 15(4).

[37] 巩建华 等. 河北省藁城市蔬菜种植区化肥施用与地下水硝酸盐污染研究. 农村生态环境, 2004, 20(1):56~59.

[38] 高旺盛 等. 黄淮海平原典型集约农区地下水硝酸盐污染初探. 生态农业研究, 1999, 7(4).

[39] 吕 耀 等. 农业生态系统中氮素造成的非点源污染. 农村环境保护. 1998, 17(1):35~39.

[40] 冷家峰 等. 济南市地下水硝酸盐污染研究. 农村生态环境, 1998, 14(1):55~57.

[41] 地下水中硝酸盐的来源. 徐志宏译自《Poultry Digest》August 1995, 24~25.

[42] 张翠云 等. 利用氮同位素技术识别石家庄市地下水硝酸盐污染源. 地球科学进展, 2004, 19(2).

[43] Aravena, R., M.L. Evans, and J.A. Cherry. Stable isotopes of oxygen and nitrogen in source identification of nitrate from septic systems. Ground water, 1993, 31(2): 180~186.

[44] Blke J K, Denver J M. Combined use of groundwater dating, chemical, and isotopic analyses to resolve the history and fate of nitrate contamination in two agricultural watersheds, Atlantic coastal plain, Maryland. Water Resources Research, 1995, 31: 2319~2339.

[45] B rrcher J, O Strebel, S Voerkelius, and H L Schmidt. Using Isotope fraction of nitrate-nitrogen and nitrate-oxygen for evaluation of microbial denitrification in a sandy aquifer. J. of Hydrology, 1990, 114: 413~424.

[46] Exner M E, and R F. Spalding. N-15 identification of nonpoint sources of nitrate contamination beneath cropland in the Nebraska Panhandle: two case studies. Applied Geochemistry, 1994, 9: 73~81.

[47] Gormly J R. and Spalding R F. Sources and concentrations of nitrate-nitrogen in groundwater of the Central Platte region, Nebraska. Groundwater, 1979, 17: 291~300.

[48] Komor S C, and H W. Anderson, Jr. Nitrogen isotope as indicators of nitrate sources in Minnesota sand-plain aquifers. Ground water, 1993, 31(2): 260~270.

[49] Mariotti A, A Landreau and B Simon. 15N isotope biogeochemistry and natural denitrification process in ground water: Application to the chalk aquifer of northern France. Geochimica et Cosmochiimica Acta, 1988, 52: 1869~1978.

[50] Rivers C N, M H Barreyy, K M Hiscock P F, Dennis N A Feast and D N Lerner. Use o nitrogen isotopes to identify nitrogen contamination of the Sherwood sandstone aquifer beneath in the city of Nottingham, United Kingdom. Hydrogeology Journal, 1996, 4(1): 90~102.

[51] Knowles R, and T H Blackburn. Nitrogen Isotope Techniques. Academic Press, Inc, 1992.

[52] Chen J Y, Tang C Y, Sakura S, Shen Y J. Nitrate pollution in groundwater in the lower reach of the Yellow River, case study in Shandong Province, China. Proceedings of the International Symposium on Ground Water Problems related to Geo-Environment, Okayama 2003, Japan by A.A.Balkema Publishers.

[53] 张翠云 等. 张掖市地下水硝酸盐污染源的氮同位素研究. 干旱区资源与环境, 2004, 18(1).

[54] 毕二平 等. 石家庄市地下水中氮污染分析. 水文地质工程地质, 2001, 2: 31~34.

[55] Chen J Y, Tang C Y, Yu JJ. Use of 18O, 2H and 15N to identify nitrate contamination of groundwater in a wastewater irrigated field near the city of Shijiazhuang, China. Journal of Hydrology, In press (doi:10.1016/j.jhydrol.2005.11.007).

[56] Donald L.Phillips et al.. 农业耕作措施对非点源污染的影响. 水土保持科技情报, 1994, (3).

[57] Jorage A.Delgado. 利用NLEAP估测覆盖作物对水质的影响. 水土保持科技情报, 1999, (3).

[58] 张维理 等. 西欧发达国家提高化肥利用率的途径, 土壤肥料, 1998(5).

[59] 崔洪波 等. 长效碳酸氢铵缓效机理与环境效应研究. 应用生态学报, 1997, 8(3).

[60] 李国学 等. 不同堆肥及其制成低浓度复混肥的环境和蔬菜效应的研究. 农业环境保护, 2000, 19(4) 200~203.

[61] 周立祥 等. 城市污泥土地利用研究. 生态学报, 1999, 19(4).

[62] 崔理华 等. 城市污水人工快滤处理后回用的环境效应研究. 农业环境保护, 1997, 16(4):153~157.

[63] 方 功 等. 滴灌施肥技术对大棚甜椒产量与土壤硝酸盐的影响. 华中农业大学学报, 2001, 20(4).

[64] 钱晓晴 等. IFC增效微肥对小白菜产量和硝酸盐积累的影响. 农村生态环境, 2003, 19(2):29~33.

[65] 胡国臣 等. 地下水硝酸盐氮污染防治研究. 农业环境保护, 1999, 18(5):228~230.

[66] 徐芳香 等. 我国地下水中硝酸盐污染防治及水源保护区划分. 污染防治技术, 1999, 12(1).

[67] 蒋雪莲. 农业氮肥对水域的污染及其防治措施. 浙江化工, 30(3).

[68] 龚闻理 等, CARIX工艺联合去除饮用水中硝酸盐和硬度. 工业水处理, 1994, 14(1).

[69] 朱 苓 等. 生物膜电极法在废水处理中的应用. 污染防治技术, 1998, 11(1).

[70] 姜 巍 等. 固定床自养反硝化去除地下水中的硝酸盐氮. 中国环境科学, 21卷.

[71] 范 彬 等. 异养-电极-生物膜联合反应器脱除地下水中硝酸盐的研究. 环境科学学报, 2001, 21(3).

[72] 曲久辉 等. 电解产氢自养反硝化去除地下水中硝酸盐氮的研究. 环境科学, 2001, 22(6).

[73] 张 胜 等. 包气带土体反硝化作用对NO3 - 转化的试验研究. 农业环境保护, 2002, 21(3):254~256.

[74] 吴耀国. 地下水环境中反硝化作用. 环境污染治理技术与设备, 2002, 3(3).

[75] 张 燕. 地下水硝酸盐污染的控制对策及去除技术. 农业环境保护, 2002, 21(2):183~184

[76] 范 彬 等. 化学反硝化法脱除地下水中的硝酸盐. 中国给水排水, 2001, 17(11).

[77] 张 燕 等.Pd-Cu/γ - Al2O3催化还原硝酸盐的研究. 催化学报, 24(4).

[78] 张少辉 等. 地下水中硝酸盐去除的新工艺.中国沼气, 2002,20(3).

[79] 硝酸盐的去除(第18届国际水道会议特别议题). 中国给水排水, 1995, 11(4).

[80] 苏 省. 地下水源净化法. 中国农村小康科技, 1997, (2).

[81] 分解水中氮化物新装置. 金属世界. 1998, (4).

[82] Rsymond J. Supalla, et al. 采用氮和水管理措施改善水质. 水土保持科技情报, 1995, (4).

[83] 陈 宁. 离子色谱法测定污水中硝酸盐氮. 理化检验——化学分册, 1998, 34(6).

[84] 罗建华 等. 一阶导数紫外分光光度法测定地下水中硝酸盐氮. 河南化工, 2000, (4).

[85] 唐仕明 等. 还原—紫外分光光度法测定水中NO3. 石油大学学报(自然科学版), 2002, 26(2).

[86] 王会法 等. 2,6-二甲酚分光光度法测定水样中的硝酸盐氮. 化工技术与开发,2003, 32(1).

[87] 张克忠 等. 催化光度法测定痕量亚硝酸根的研究——溴酸钾-结晶紫体系. 分析试验室, 1998, 17(3).

[88] 张克忠 等. 催化光度法测定痕量亚硝酸根的研究——溴酸钾-维多利亚蓝B体系. 理化检验——化学分册, 1998, 34(6).

[89] 訾言勤 等. 非平衡流动注射光度法测定微量亚硝酸根的研究. 分析测试学报, 2000, 19(2).

[90] 赵燮京 等. 硝酸根电极法测定地下水中亚硝酸盐氮的研究. 西南农业学报, 1999, 12卷(土肥专辑).

[91] 李贵敏 等. 用新紫外光度法测定水中亚硝酸盐氮的研究. 化学研究, 2001, 12(3).

[92] 李党生 等. 碱性品红紫外光度法测定水中亚硝酸盐氮. 环境工程, 2002, 20(2).

[93] 丛陪凯 等. 硝酸态氮引起的地下水污染对人体健康的影响. 山东环境, 2001, (106).

[94] 陈余道 等. 淄博市大武水源地地下水中苯的归宿与治理建议, 1998, 43(1).

[95] 张 权 等. 王哥庄湾陆源硝酸盐氮输送通量研究. 海洋环境科学, 2002, 21(2).

文章导航

/